Immobilization and Study of Homogeneous Catalysts in a Continuous Flow Reactor Using Inorganic Particles Coated with Polymer
Immobilization and Study of Homogeneous Catalysts in a Continuous Flow Reactor Using Inorganic Particles Coated with Polymer
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DOI：
10.1007/s10562-022-04056-6
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发表时间：
2022-06
影响因子：
2.8
通讯作者：
Nicholas M. Wang;Sam Dillon;Damien Guironnet
中科院分区：
文献类型：
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作者：
Nicholas M. Wang;Sam Dillon;Damien Guironnet
我们证明，有机金属催化剂可以固定在气相填充床反应器（PBR）的无机粒子与非挥发性聚合物催化剂溶液的涂层。我们通过钌钳配合物催化的乙醇偶联反应（Guerbet反应）和铱配合物催化的己烯加氢反应的案例研究验证了该方法。我们对该技术的实施有助于启发采用先进的反应器工程策略来研究均相催化剂。图形摘要
We demonstrated that organometallic catalysts can be immobilized in a gas-phase packed bed reactor (PBR) by coating inorganic particles with a non-volatile polymer-catalyst solution. We validated the methodology through a case study on the ethanol coupling reaction (Guerbet reaction) catalyzed by a ruthenium pincer complex and on the hydrogenation of hexene catalyzed by an iridium complex. Our implementation of this technique serves to inspire the adoption of advanced reactor engineering strategies for the study of homogeneous catalysts.Graphical abstract