Oxidation of cis- and trans-pinane with RuO4 generated in situ
Oxidation of cis- and trans-pinane with RuO4 generated in situ
复制标题
原位生成的 RuO4 氧化顺式和反式蒎烷
DOI：
10.1016/0020-1693(94)03900-3
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发表时间：
1994
影响因子：
2.8
通讯作者：
B. Waegell
中科院分区：
文献类型：
--
作者：
J. Coudret;B. Waegell
本文对原位生成的RuO_4氧化顺式和反式蒎烷（1a和1b）的产物进行了分析。对它们的结构的研究表明，有两种机制在起作用：一种是我们假设的协调机制，另一种是巴基认为的更有活力的机制，它涉及到要氧化的碳上部分正电荷的发展。
The products obtained by oxidation ofcis- andtrans-pinane (1aand1b) by RuO4generatedin situhave been analyzed. Examination of their structure shows that two mechanisms are operating: a concerted mechanism postulated by ourselves and a more energetic mechanism considered by Bakke, which involves the development of a partial positive charge on the carbon to be oxidized.