Luminescence enhancement of ruthenium complexes in polymer nanosheet by surface plasmon resonance of metal nanoparticle

Luminescence enhancement of ruthenium complexes in polymer nanosheet by surface plasmon resonance of metal nanoparticle
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DOI:
10.1246/cl.2005.1246
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发表时间:
2005-09-05
期刊:
影响因子:
1.6
通讯作者:
Miyashita, T
Miyashita, T
中科院分区:
化学4区
文献类型:
--
作者:
Tanaka, H;Mitsuishi, M;Miyashita, T

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描述了掺入聚合物 Langmuir Blodgett (LB) 薄膜(聚合物纳米片)中的三(2,2'-联吡啶)钌络合物(Ru(bpy)(3)(2+))在金属纳米颗粒上由局域表面等离激元激发的发光特性。清楚地表明Ru(bpy)(3)(2+)的发光强度随着距纳米颗粒上局域表面等离子体的距离而变化。观察到银纳米颗粒对发光的增强和金纳米颗粒对发光的猝灭。
The luminescence properties of tris(2,2'-bipyridine) ruthenium complex (Ru(bpy)(3)(2+)) incorporated into polymer Langmuir Blodgett (LB) films (polymer nanosheets) excited by localized surface plasmon on metal nanoparticles are described. It was clearly demonstrated that the luminescence intensity of Ru(bpy)(3)(2+) was changed by the distance from the localized surface plasmon on the nanoparticle. The enhancement of luminescence by silver nanoparticle and the quenching of luminescence by gold nanoparticle were observed.