Comment on ‘‘Self‐nucleation in the sulfuric acid–water system’’
Comment on ‘‘Self‐nucleation in the sulfuric acid–water system’’
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对“硫酸-水系统中的自成核”的评论
DOI：
10.1063/1.442201
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发表时间：
1981
期刊：
影响因子：
--
通讯作者：
R. Bone
中科院分区：
文献类型：
--
作者：
R. Renninger;F. Hiller;R. Bone
Doyle [J. Chem. Phys. 35，795（1961）]在双组分液滴的自由能表面上寻找平衡鞍点的技术受到了批评。他的方法涉及到修改的拉普拉斯方程内的超压液滴和开尔文方程的过剩蒸汽压的组成部分。这些变化不正确地解释了表面张力随组成的变化。
The technique of Doyle [J. Chem. Phys. 35, 795 (1961)] for finding the equilibrium saddle point on the free energy surface of a two‐component liquid droplet is criticized. His method is related to modifications of the Laplace equation for the excess pressure inside a droplet and the Kelvin equation for the excess vapor pressure of its constituents. These changes incorrectly account for the variation of surface tension with composition.