Diaqua-{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III) perchlorate 18-crown-6 hemisolvate monohydrate.
Diaqua-{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III) perchlorate 18-crown-6 hemisolvate monohydrate.
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Diaqua-{6,6-二甲氧基-2,2-[乙烷-1,2-二基双(次氮基甲基-丁炔)]二苯酚-γO,N,N,O}高氯酸锰(III)
DOI：
10.1107/s1600536808044176
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发表时间：
2009
期刊：
影响因子：
--
通讯作者：
Yu,Ming-Ming
中科院分区：
文献类型：
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作者：
Li,Zhan-Xian;Li,Xia;Zhang,Li-Feng;Yu,Ming-Ming
In the cation of the title compound, [Mn(C18H18N2O4)(H2O)2]ClO4·0.5C12H24O6·H2O, the MnIII ion is coordinated by two water O atoms, and two O atoms and two N atoms from the tetradentate 6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolate ligand, completing a distorted octahedral geometry. One O atom of the 18-crown-6-ether is disordered over two positions with occupancies of 0.70 (2) and 0.30 (2).
