Water-Vapor-Induced Reversible Switching of Electronic States in an MMX-Type Chain Complex with Retention of Single Crystallinity
Water-Vapor-Induced Reversible Switching of Electronic States in an MMX-Type Chain Complex with Retention of Single Crystallinity
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DOI：
10.1002/anie.200905608
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发表时间：
2010-01-01
影响因子：
16.6
通讯作者：
Kuroda, Shin-ichi
中科院分区：
文献类型：
--
作者：
Iguchi, Hiroaki;Takaishi, Shinya;Kuroda, Shin-ichi
（如图所示）来回：准 1D 双核 Pt 配合物随着脱水和再水合而发生可逆的结构变化和物理性质的变化。脱水后，电子态从交替电荷极化和电荷密度波 (ACP+ CDW) 态转变为窄能隙 CDW 态，室温下电导率和摩尔自旋敏感性增加。
(Figure Presented) Back and forth: Reversible structural change and changes in the physical properties of a quasi-1 D dinuclear Pt complex occurred with dehydration and rehydration. Upon dehydration, the electronic state changed from an alternating charge-polarization and charge-density-wave (ACP+ CDW) state to a narrow-gapped CDW state with an increase in the electrical conductivity and molar spin susceptibility at room temperature.