Metal complexes of Co, Ni and Cu with the pincer ligand HN(CH2CH2P(i)Pr2)2: preparation, characterization and electrochemistry.
Metal complexes of Co, Ni and Cu with the pincer ligand HN(CH2CH2P(i)Pr2)2: preparation, characterization and electrochemistry.
复制标题
Co、Ni 和 Cu 与钳配体 HN(CH2CH2P(i)Pr2)2 的金属配合物：制备、表征和电化学。
作者：
S. S. Rozenel;J. Kerr;J. Arnold
合成了一系列Co、Ni、Cu与配体HN（CH（2）CH（2）P（i）Pr（2））（2）（HNP（2））的配合物，用循环伏安法研究了它们的电化学行为。镍配合物[（HNP（2））NiOTf]OTf和[（HNP（2））NiNCCH（3）]（BF（4））（2）显示可逆还原，相关酰胺衍生物（NP（2））NiBr也是如此。相关的铜（I）和钴（II）衍生物也被分离和表征。哌啶与[（HNP（2））NiNCCH（3）]（BF（4））（2）的加成导致新物种[（HNP（2））Ni（N（H）C（CH（3））NC（5）H（10））]（BF（4））（2）的形成。[（HNP（2））NiNCCH（3）]（BF（4））（2）催化哌啶与乙腈亲核加成生成HN=C（CH（3））NC（5）H（10）.
A series of Co, Ni and Cu complexes with the ligand HN(CH(2)CH(2)P(i)Pr(2))(2) (HNP(2)) has been isolated and their electrochemical behaviour investigated by cyclic voltammetry. The nickel complexes [(HNP(2))NiOTf]OTf and [(HNP(2))NiNCCH(3)](BF(4))(2) display reversible reductions, as does the related amide derivative (NP(2))NiBr. The related copper(I) and cobalt(II) derivatives were also isolated and characterized. The addition of piperidine to [(HNP(2))NiNCCH(3)](BF(4))(2) led to the formation of the new species [(HNP(2))Ni(N(H)C(CH(3))NC(5)H(10))](BF(4))(2). The nucleophilic addition of piperidine to acetonitrile to produce HN=C(CH(3))NC(5)H(10) was found to be catalyzed by [(HNP(2))NiNCCH(3)](BF(4))(2).