A convenient synthesis of diaminoglyoxime and diaminofurazan: Useful precursors for the synthesis of high density energetic materials
A convenient synthesis of diaminoglyoxime and diaminofurazan: Useful precursors for the synthesis of high density energetic materials
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DOI：
10.1002/jhet.5570320452
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发表时间：
1995-07
影响因子：
2.4
通讯作者：
A. Gunasekaran;T. Jayachandran;J. H. Boyer;M. Trudell
中科院分区：
文献类型：
--
作者：
A. Gunasekaran;T. Jayachandran;J. H. Boyer;M. Trudell
Abstract : The reaction of glyoxime (4) and hydroxylamine hydrochloride in aqueous sodium hydroxide was found to be a safe and inexpensive method for the preparation of multigram quantities of diaminoglyoxime (5). Potassium hydroxide mediated dehydration of 5 furnished diaminofurazan (1) in good yield of exceptional purity. The ready availability of 1 and 5 has facilitated the synthesis of new energetic furazan derivative MNOTO (B). jg
