Modification of cloud condensation nucleus activity of organic aerosols by hydroxyl radical heterogeneous oxidation

Modification of cloud condensation nucleus activity of organic aerosols by hydroxyl radical heterogeneous oxidation
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DOI:
10.1016/j.atmosenv.2009.06.043
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发表时间:
2009-10-01
影响因子:
5
通讯作者:
Abbatt, J. P. D.
Abbatt, J. P. D.
中科院分区:
环境科学与生态学2区
文献类型:
--
作者:
George, I. J.;Chang, R. Y. -W.;Abbatt, J. P. D.

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研究了OH自由基对饱和有机颗粒非均相氧化后云凝结核(CCN)活性的影响。将亚微米癸二酸二(2-乙基己基)酯(BES)和硬脂酸颗粒暴露于反应器流管中的OH自由基,并监测CCN活性。单分散硬脂酸和尺寸为145-150 nm的BES颗粒的吸湿参数K从100 nm增加到100 nm。
The modification of cloud condensation nucleus (CCN) activity of saturated organic particles resulting from heterogeneous oxidation by OH radicals was studied. Submicron Bis-2-ethylhexyl sebacate (BES) and stearic acid particles were exposed to OH radicals in a reactor flow tube and CCN activity was monitored. The hygroscopicity parameter, K, for monodisperse stearic acid and BES particles of 145-150 nm in size increased from