Synthesis and Reactivity of Ruthenium Complexes Bearing Arsenic-Containing Arsenic-Nitrogen-Arsenic-Type Pincer Ligand
Synthesis and Reactivity of Ruthenium Complexes Bearing Arsenic-Containing Arsenic-Nitrogen-Arsenic-Type Pincer Ligand
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DOI：
10.1021/om5006116
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发表时间：
2014-09
期刊：
影响因子：
2.8
通讯作者：
Yoshiaki Tanabe;S. Kuriyama;Kazuya Arashiba;K. Nakajima;Y. Nishibayashi
中科院分区：
文献类型：
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作者：
Yoshiaki Tanabe;S. Kuriyama;Kazuya Arashiba;K. Nakajima;Y. Nishibayashi
设计、制备了带有含砷砷-氮-砷 (ANA) 型钳配体的双核和单核钌配合物，并通过 X 射线分析对其进行了表征。两种钌配合物都是醇脱氢转化的有效催化剂。
Dinuclear and mononuclear ruthenium complexes bearing an arsenic-containing arsenic-nitrogen-arsenic (ANA)-type pincer ligand are designed, prepared, and characterized by X-ray analyses. Both ruthenium complexes work as effective catalysts toward dehydrogenative transformations of alcohols.