C-H•••O non-classical hydrogen bonding in the stereomechanics of organic transformations: theory and recognition
C-H•••O non-classical hydrogen bonding in the stereomechanics of organic transformations: theory and recognition
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DOI：
10.1039/c3ob40828k
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发表时间：
2013-08-21
影响因子：
3.2
通讯作者：
Cheong, Paul Ha-Yeon
中科院分区：
文献类型：
--
作者：
Johnston, Ryne C.;Cheong, Paul Ha-Yeon
这份手稿描述了非经典氢键（NCHBs），特别是C-H中心点中心点O相互作用，在现代合成有机转化中的作用。我们的目标是指出开创性的例子，C-H中心点O的相互作用已被调用作为一个关键的立体控制元素，并提供预测价值，在认识未来和/或潜在的C-H中心点O的相互作用在现代转型。
This manuscript describes the role of non-classical hydrogen bonds (NCHBs), specifically C-H center dot center dot center dot O interactions, in modern synthetic organic transformations. Our goal is to point out the seminal examples where C-H center dot center dot center dot O interactions have been invoked as a key stereocontrolling element and to provide predictive value in recognizing future and/or potential C-H center dot center dot center dot O interactions in modern transformations.