Determination of hydrophobicity scale of tetraphenylborate and its derivatives by ferrocene based three-phase electrodes
Determination of hydrophobicity scale of tetraphenylborate and its derivatives by ferrocene based three-phase electrodes
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二茂铁基三相电极测定四苯硼酸盐及其衍生物的疏水性规模
DOI：
10.1016/j.elecom.2014.11.005
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发表时间：
2015
影响因子：
5.4
通讯作者：
H. B. Shao
中科院分区：
文献类型：
--
作者：
K. K. Hu;B. Xu;H. B. Shao
In three-phase electrodes (TPE), ferrocene (Fc) was often thought to be useless for ion transfer injection because its oxidized form has very low affinity for organic phase. Instead, lipophilic decamethylferrocene (DMFc) was employed as a better probe for the ion transfer study. However, our present results indicate that the commonly-used DMFc based TPE was not applicable for the transfer of strong hydrophobic tetraphenylborate and its derivatives (TPBs); whereas the developed Fc based TPE can meet this special requirement. Taking this advantage, we firstly evaluate the standard ion transfer energies of these TPBs and get a full knowledge of their hydrophobicity scale, which will benefit the related areas such as hydrophobic ionic liquids and lipophilic anion exchangers.
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影响因子：
6.2
作者：
BAKKER, E;PRETSCH, E
通讯作者：
PRETSCH, E
影响因子：
1.6
作者：
Nishi, Naoya;Murakami, Hiroshi;Kakiuchi, Takashi
通讯作者：
Kakiuchi, Takashi
影响因子：
4
作者：
Yasuichiro Shiraki;K. Onitsuka;K. Takuma;T. Sonoda;H. Kobayashi
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Yasuichiro Shiraki;K. Onitsuka;K. Takuma;T. Sonoda;H. Kobayashi
影响因子：
4
作者：
Naoya Nishi;A. Suzuki;T. Kakiuchi
通讯作者：
Naoya Nishi;A. Suzuki;T. Kakiuchi
影响因子：
1.8
作者：
Z. Samec;J. Langmaier;T. Kakiuchi
通讯作者：
Z. Samec;J. Langmaier;T. Kakiuchi