An Efficient Rhodium/Oxygen Catalytic System for Oxidative Heck Reaction of Indoles and Alkenes via C-H Functionalization
An Efficient Rhodium/Oxygen Catalytic System for Oxidative Heck Reaction of Indoles and Alkenes via C-H Functionalization
复制标题
通过 C-H 官能化实现吲哚和烯烃氧化 Heck 反应的高效铑/氧催化体系
DOI：
10.1002/adsc.201301107
复制
发表时间：
2014
影响因子：
5.4
通讯作者：
Huang Hanmin
中科院分区：
文献类型：
--
作者：
Yang Lei;Zhang Guoying;Huang Hanmin
以分子氧为唯一氧化剂，铑（III）催化吲哚与烯烃的直接选择性C-2烯基化反应。铑/氧催化体系适用于广泛的吲哚和烯烃，为制备各种C-2烯基化吲哚和吡咯提供了新的途径。
A rhodium(III)‐catalyzed direct selective C‐2 alkenylation reaction of indoles with alkenes has been developed with molecular oxygen as the sole oxidant. The rhodium/oxygen catalytic system is applicable to a broad range of indoles and alkenes, which provides a novel access to various C‐2 alkenylated indoles and pyrroles.