Modulation of proton conductivity in coordination polymer mixed glasses
Modulation of proton conductivity in coordination polymer mixed glasses
复制标题
配位聚合物混合玻璃中质子电导率的调节
DOI：
10.1039/d2cc01266a
复制
发表时间：
2022
影响因子：
4.9
通讯作者：
Horike Satoshi
中科院分区：
文献类型：
--
作者：
Thanaphatkosol Chonwarin;Ma Nattapol;Kageyama Kotoha;Watcharatpong Teerat;Tiyawarakul Thanakorn;Kongpatpanich Kanokwan;Horike Satoshi
配位聚合物玻璃中的可逆固-液相变允许从两种不同的母体化合物形成均匀的混合玻璃。由此产生的混合玻璃显示组成依赖的玻璃化转变温度和独特的粘弹性行为。一个非线性的混合玻璃前体的效果和可控的无水H+电导率也被证明。
Reversible solid-to-liquid phase transition in coordination polymer glasses allowed the formation of homogeneous mixed-glasses from two distinct parent compounds. The resulting mixed glasses show composition-dependent glass transition temperatures and unique viscoelastic behaviour. A non-linear mixed glass former effect and controllable anhydrous H+ conductivities are also demonstrated.