Synthetic Routes to Stimuli‐Responsive Micelles, Vesicles, and Surfaces via Controlled/Living Radical Polymerization
Synthetic Routes to Stimuli‐Responsive Micelles, Vesicles, and Surfaces via Controlled/Living Radical Polymerization
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DOI：
10.1080/15583720600945428
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发表时间：
2006-11
期刊：
影响因子：
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通讯作者：
C. McCormick;Stacey E. Kirkland;Adam W. York
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文献类型：
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作者：
C. McCormick;Stacey E. Kirkland;Adam W. York
可控/活性聚合（CLRP）技术最近已经开发出来，为合成具有精确定制的纳米和微米尺度特征的材料提供了前所未有的机会。该帐户侧重于刺激响应嵌段共聚物领域的重大发展，在先进的配方和表面科学中具有即时和未来的实用性。具体地，描述了用于制备响应性胶束和囊泡、稳定的纳米颗粒、薄膜、聚合物刷和其他有序结构的稳定自由基聚合（SFRP）、原子转移聚合（ATRP）和可逆加成断裂链转移（RAFT）聚合技术。响应于外部刺激的构象变化表现为理化性质的变化，包括表面润湿性、吸附性、粘附性、润滑性和渗透性。* 题为"水溶性聚合物“系列的第120号论文。
Controlled/living polymerization (CLRP) techniques have recently been developed that offer unprecedented opportunities for synthesis of materials with precisely tailored nano‐ and micro‐scale features. This account focuses on significant developments in the field of stimuli‐responsive block copolymers with immediate and future utility in advanced formulation and surface science. Specifically, stable free radial polymerization (SFRP), atom transfer polymerization (ATRP), and reversible addition fragmentation chain transfer (RAFT) polymerization techniques for preparation of responsive micelles and vesicles, stabilized nanoparticles, thin films, polymer brushes, and other ordered structures are described. Conformational changes in response to external stimuli are manifested in changes in physiochemical properties including surface wetting, adsorption, adhesion, lubricity, and permeability. *Paper number 120 in a series entitled Water Soluble Polymers.