Synthesis and reactions of some dinitrodiazoquinones

Synthesis and reactions of some dinitrodiazoquinones
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DOI:
10.1016/s0040-4020(99)00223-9
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发表时间:
1999-04-23
期刊:
影响因子:
2.1
通讯作者:
Brimert, T
Brimert, T
中科院分区:
化学3区
文献类型:
--
作者:
Bergman, J;Brimert, T

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Some novel highly substituted diazoquinones have been synthesised in one step from simple anilines by treatment with nitric acid in sulfuric acid solution. The reaction is proposed to proceed via an N,3,4,5-tetranitroaniline which on its reaction pathway undergoes a nitro-nitrito rearrangement. (C) 1999 Elsevier Science Ltd. All rights reserved.