Ionic Polyacetylene with Aromatic Functional Groups : Synthesis and Properties
Ionic Polyacetylene with Aromatic Functional Groups : Synthesis and Properties
复制标题
具有芳香族官能团的离子聚乙炔：合成与性能
DOI：
10.1002/macp.200800284
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发表时间：
2008
影响因子：
2.5
通讯作者：
Y. Gal
中科院分区：
文献类型：
--
作者：
G. Kwak;Sung‐Ho Jin;Jongwook Park;Y. Gal
以4-(甲硫基)苄基溴为原料，在不添加任何引发剂或催化剂的情况下，通过2-乙炔基吡啶的活化聚合反应合成了具有芳香族官能团的离子共轭聚合物聚{2-乙炔基-N-[4-(甲硫基)苄基溴化吡啶鎓]}。聚合反应在DMF、DMSO、NMP和吡啶等极性溶剂中进行得很好，并且产率很高。 NMR、IR和UV-vis光谱证实了含有N-(4-(甲硫基)苄基溴化吡啶作为取代基的共轭聚合物主链体系。该聚合物的光致发光最大峰位于508 nm，对应的光子能级为2.44 eV。该聚合物的环伏安图在-1.32至1.92 V区域表现出电化学稳定窗口。
An ionic conjugated polymer with aromatic functional groups, poly{2-ethynyl-N-[4-(methylthio)benzylpyridinium bromide]}, was synthesized via the activated polymerization of 2-ethynylpyridine by using 4-(methylthio)benzyl bromide without any additional initiator or catalyst. The polymerization proceeded well in polar solvents such as DMF, DMSO, NMP and pyridine, and produced high yields. NMR, IR, and UV-vis spectroscopy confirmed a conjugated polymer backbone system containing N-(4-(methylthio)benzylpyridinium bromide as substituents. The photoluminescence maximum peak of the polymer was located at 508 nm, which corresponds to the photon energy level of 2.44 eV. The cyclovoltammograms of the polymer exhibited an electrochemically stable window in the -1.32 to 1.92 V region.