Analysis of experimental constraints and. variables for time resolved detection of Fourier transform electrochemical impedance spectra
Analysis of experimental constraints and. variables for time resolved detection of Fourier transform electrochemical impedance spectra
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DOI：
10.1016/j.electacta.2003.12.051
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发表时间：
2004-07-15
影响因子：
6.6
通讯作者：
Roy, D
中科院分区：
文献类型：
--
作者：
Garland, JE;Pettit, CM;Roy, D
通过使用傅里叶变换（FT）技术，可以在直流电压控制的表面反应发生期间在真实的时间中执行电化学阻抗谱。在这种方法中获得的数据，作为直流控制变量的函数的一系列奈奎斯特图，可以提供关于表面动力学的丰富的时间分辨信息。我们详细讨论了这样的时间分辨实验的理论和实验考虑。我们主要集中在新的数据采集电子的背景下，在过去几年中成为可用的测量的限制和标准。我们还提出了样品的实验结果的金电极。(C)2004爱思唯尔有限公司保留所有权利。
By using the Fourier transform (FT) technique, it is possible to perform electrochemical impedance spectroscopy in real time during the occurrence of DC voltage controlled surface reactions. The data obtained in this approach, a series of Nyquist plots as functions of DC control variables, can provide a wealth of time resolved information about Surface kinetics. We discuss in detail the theoretical and experimental considerations for such time resolved experiments. We focus primarily on the constraints and criteria of measurements in the context of new data acquisition electronics that became available during the last few years. We also present sample experimental results for a gold electrode. (C) 2004 Elsevier Ltd. All rights reserved.