N‐Heterocyclic Carbene Mediated Reformatsky Reaction of Aldehydes with α‐Trimethylsilylcarbonyl Compounds.

N‐Heterocyclic Carbene Mediated Reformatsky Reaction of Aldehydes with α‐Trimethylsilylcarbonyl Compounds.
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DOI：
10.1002/chin.201323061
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发表时间：
2013-06
期刊：
ChemInform
影响因子：
--
通讯作者：
Xiaodong Zou;Guangfen Du;Wan Sun;Lin He;Xiaowei Ma;Chengzhi Gu;B. Dai
Xiaodong Zou;Guangfen Du;Wan Sun;Lin He;Xiaowei Ma;Chengzhi Gu;B. Dai
中科院分区：
其他
文献类型：
--
作者：
Xiaodong Zou;Guangfen Du;Wan Sun;Lin He;Xiaowei Ma;Chengzhi Gu;B. Dai

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假设NHC攻击（II）的硅原子以形成可能的六价硅中间体，其可以引发加成到相应的醛中。
It is assumed that the NHC attacks the silicon atom of (II) in order to form a possible hexavalent silicon intermediate, that could initiate the addition to the respective aldehyde.