Polyoxometalate-organic hybrid molecules as amphiphilic emulsion catalysts for deep desulfurization.
Polyoxometalate-organic hybrid molecules as amphiphilic emulsion catalysts for deep desulfurization.
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DOI：
10.1002/chem.201201551
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发表时间：
2012-07
期刊：
影响因子：
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通讯作者：
Panchao Yin;Joy H. Wang;Zicheng Xiao;Pingfan Wu;Yongge Wei;Tianbo Liu
中科院分区：
文献类型：
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作者：
Panchao Yin;Joy H. Wang;Zicheng Xiao;Pingfan Wu;Yongge Wei;Tianbo Liu
如此逼真：合成了两种六钒酸盐-有机杂化物，并通过在水和非极性有机溶剂的混合物中形成乳液证实了它们的两亲性，并在深度脱硫反应中用作“乳液催化剂”（见图）。它们的催化活性表现出pH依赖性，这可以通过乳液的尺寸变化和反相乳液的出现来解释。
So emulsional: Two hexavanadate-organic hybrids were synthesized and their amphiphilic properties were confirmed by forming emulsions in mixtures of water and nonpolar organic solvents, and were utilized as "emulsion catalysts" in deep desulfurization reactions (see figure). Their catalytic activities show a pH-dependent behavior, which can be explained by the size-change of emulsions and the appearance of reverse emulsions.