Chemical Dynamics in Condensed Phases
Chemical Dynamics in Condensed Phases
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DOI：
10.1093/oso/9780198529798.001.0001
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发表时间：
2006-06
期刊：
影响因子：
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通讯作者：
A. Nitzan
中科院分区：
文献类型：
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作者：
A. Nitzan
这第二版建立在第一，提供了一个统一的方法，在凝聚相分子系统的动力学过程的研究中遇到的各种问题。它侧重于三个主题：涵盖所需的背景材料，深入介绍方法，分析复杂系统中物理、化学和生物现象重要过程的几个关键应用。第一章首先对基本的数学和物理方法进行了概述。接下来是量子动力学（第2章）、辐射-物质相互作用（第3章）、固体（第4章）和液体（第5章）的介绍性章节。第6-12章提供了主要方法论的广泛覆盖：时间相关函数（第6章），随机过程（第7和8章），量子弛豫现象（第9和10章），线性响应理论（第11章）和各种形式的自旋玻色子模型描述分子与辐射场和热环境的相互作用（第12章）。第13-19章描述了一些关键应用：振动弛豫和振动能量转移（第13章）势垒穿越和扩散控制反应（第14章），溶剂化动力学（第15章），本体溶剂中的电子转移（第16章）和电极/电解质和金属/分子/金属结（第17章），以及与凝聚相（第18章）和介电界面（新第19章）的分子光谱学有关的几个过程。
This second edition builds on the first, providing a uniform approach to diverse problems encountered in the study of dynamical processes in condensed-phase molecular systems. It focuses on three themes: coverage of needed background material, in-depth introduction of methodologies, and analysis of several key applications to processes of importance in physical, chemical and biological phenomena in complex systems. Chapter 1 starts with a general review of basic mathematical and physical methods. It is followed by a few introductory chapters on quantum dynamics (Chapter 2), radiation–matter interaction (Chapter 3) and introduction to solids (Chapter 4) and liquids (Chapter 5). Chapters 6–12 provide a broad coverage of the main methodological approaches: time-correlation functions (Chapter 6), stochastic processes (Chapters 7 and 8), quantum relaxation phenomena (Chapters 9 and 10), linear response theory (Chapter 11) and various forms of the spin–boson model for describing molecular interaction with the radiation field and the thermal environment (Chapter 12). Chapters 13–19 describe some key applications: Vibrational relaxation and vibrational energy transfer (Chapter 13), Barrier crossing and diffusion-controlled reactions (Chapter 14), solvation dynamics (Chapter 15), electron transfer in bulk solvents (Chapter 16) and at electrodes/electrolyte and metal/molecule/metal junctions (Chapter 17), and several processes pertaining to molecular spectroscopy in condensed phases (Chapter 18) and at dielectric interfaces (new Chapter 19).