Augmenting metallobasicity to modulate gold hydrogen bonding
Augmenting metallobasicity to modulate gold hydrogen bonding
复制标题
增强金属碱度以调节金氢键
DOI：
10.1039/d2cc03328c
复制
发表时间：
2022
影响因子：
4.9
通讯作者：
Gabbaï, François P.
中科院分区：
文献类型：
--
作者：
Maltz, Logan T.;Wilkins, Lewis C.;Gabbaï, François P.
本文报道了两种用于分子内Au H-O氢键的膦金甲醇配合物的合成和表征。通过氯化物苯基配体取代增加金的金属碱性产生了可观察到的增加，这是实验和计算分析的氢键的强度。
We report the synthesis and characterization of two phosphine gold carbinol species designed to support intramolecular Au⋯H–O hydrogen bonding. Increasing the metallobasicity of gold through chloride to phenyl ligand substitution produced an observable increase in this hydrogen bond's strength which was analyzed experimentally and computationally.