Organocatalyzed cyclizations of π-allylpalladium complexes:: A new method for the construction of five- and six-membered rings

Organocatalyzed cyclizations of π-allylpalladium complexes:: A new method for the construction of five- and six-membered rings
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DOI:
10.1021/ol7023554
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发表时间:
2007-11-22
期刊:
影响因子:
5.2
通讯作者:
Saicic, Radomir N.
Saicic, Radomir N.
中科院分区:
化学1区
文献类型:
--
作者:
Bihelovic, Filip;Matovic, Radomir;Saicic, Radomir N.

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有机过渡金属催化和有机催化的协同结合首次实现了醛的Tsuji-Trost环化。催化不对称反应的变体也是可能的。
Synergic combination of organotransition metal catalysis and organocatalysis allows, for the first time, the Tsuji-Trost cyclization of aldehydes. A catalytic asymmetric variant of the reaction is also possible.