High‐resolution Fourier transform Raman spectra of the fundamental bands of 14N15N and 15N2
High‐resolution Fourier transform Raman spectra of the fundamental bands of 14N15N and 15N2
复制标题
14N15N 和 15N2 基带的高分辨率傅里叶变换拉曼光谱
DOI：
10.1002/jrs.785
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发表时间：
2001
影响因子：
2.5
通讯作者：
J. Bendtsen
中科院分区：
文献类型：
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作者：
J. Bendtsen
以0.02 cm-1的分辨率测量14 N15 N和15 N2的基本带的傅里叶变换拉曼光谱。观察并测量所有分支（O，Q，S）的线条。对波数的分析得到了带源ν0（14 N15 N）= 2291.33773（8）cm−1和ν0（15 N2）= 2252.07846（9）cm−1的改进值，以及两个分子基态和第一激发态的转动参数的改进值。14 N15 N的测量值分别为B 0 = 1.9236102（35）cm−1和D 0 = 5.3530（94）× 10−6 cm−1，B1 − B 0 = −0.01651064（86）cm−1和D1 − D 0 = 1.06（16）× 10−8 cm−1。对于15 N2，得到的值为B 0 = 1.8576250（36）cm−1，D 0 = 4.9760（87），B1 − B 0 = 0.01566657（99）cm−1和D1 − D 0 = 0.94（18）× 10−8 cm−1。所有三种同位素的分子氮计算的键长显示出系统的减少，随着分子量的增加。版权所有© 2001约翰威利父子有限公司。
The Fourier transform Raman spectra of the fundamental bands of 14N15N and 15N2 were measured with a resolution of 0.02 cm−1. Lines from all branches (O, Q, S) were observed and measured. The analyses of the wavenumbers yield improved values for the band origins ν0(14N15N) = 2291.33773(8) cm−1 and ν0(15N2) = 2252.07846(9) cm−1 and improved values for the rotational parameters of the ground state and the first excited state of the two molecules. The values obtained for 14N15N are B0 = 1.9236102(35) cm−1 and D0 = 5.3530(94) × 10−6 cm−1 and B1 − B0 = −0.01651064(86) cm−1 and D1 − D0 = 1.06(16) × 10−8 cm−1. For 15N2 the following values obtained are B0 = 1.8576250(36) cm−1, D0 = 4.9760(87), B1 − B0 = 0.01566657(99) cm−1 and D1 − D0 = 0.94(18) × 10−8 cm−1. The bond length calculated for all three isotopomers of molecular nitrogen shows a systematic decrease with increasing molecular mass. Copyright © 2001 John Wiley & Sons, Ltd.
使用相干反斯托克斯拉曼光谱的太赫兹生物光子学
DOI：
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发表时间：
2007
期刊：
Proc. of 4th International Symposium on System Construction of Global-Network-Oriented Information Electroniccs 120
影响因子：
--
作者：
Y.Inouye;N.Hayazawa;P.Verma;S.Kawata;Akinori Ohshita;Akinori Ohshita;Aikinori Ohshita;Akinori Ohshita;辰巳剛平;Akinori Ohshita;松屋千春;松屋千春;松屋千春;Akinori Ohshita;Gohei Tatsumi;Akinori Oshita;Chiharu Matsuya;Chiharu Matsuya;Chiharu Matsuya;畑 浩一;Akinori Ohshita;松屋千春;松屋千春;松屋千春;Akinori Ohshita;松屋千春;畑 浩一;Koichi Hata;Koichi Hata;Masaaki Okuhara;Akinori Ohshita;松屋千春;Koichi Hata;Masaaki Okuhara;Akinori Ohshita;Chiharu Matsuya;Masaaki Okuhara;Akinori Ohshita;S.Hayashi;K.M.Abedin;S.Hayashi;K.M.Abedin;Jun-ichi Shikata
通讯作者：
Jun-ichi Shikata