A diselenide additive enables photocatalytic hydroalkoxylation of gem-difluoroalkenes.
A diselenide additive enables photocatalytic hydroalkoxylation of gem-difluoroalkenes.
复制标题
二硒化物添加剂能够实现偕二氟烯烃的光催化加氢烷氧基化。
DOI：
10.1039/d3cc01012k
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发表时间：
2023
期刊：
影响因子：
--
通讯作者：
Altman,RyanA
中科院分区：
文献类型：
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作者：
Herrick,RyanM;AbdEl-Gaber,MohammedK;Coy,Gabriela;Altman,RyanA
A photocatalytic hydroalkoxylation reaction enables the coupling of aliphatic alcohols with gem-difluoroalkenes, expanding the scope of accessible α,α-difluorinated ethers, a desirable substructure for medicinal and agricultural chemists. This reaction exploits an uncommon diselenide co-catalyst to facilitate the net hydrofunctionalization process, which contrasts alternate single-electron reactions that deliver dioxidation products. Future use of this co-catalyst might enable other currently unknown photocatalytic reactions.
