A 2-Iodobenzamide Catalyst for Oxidation of Alcohols at Room Temperature
A 2-Iodobenzamide Catalyst for Oxidation of Alcohols at Room Temperature
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室温下醇氧化的 2-碘苯甲酰胺催化剂
DOI：
10.1002/ajoc.201300279
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发表时间：
2014
期刊：
影响因子：
--
通讯作者：
H.
中科院分区：
文献类型：
--
作者：
Yakura;T.; Yamada;A.; Noda;N,; Fujiwara;T.; Nambu;H.
研制了一种用于醇氧化反应的2-碘苯甲酰胺催化剂。醇与2-碘苯甲酰胺在氧酮为助氧化剂的存在下，在室温下反应，以极高的产率得到了相应的羰基化合物。伯醇直接转化为相应的羧酸，而仲醇被氧化为酮。2-碘苯甲酸型乙醇常温氧化催化剂尚未见报道。
A 2‐iodobenzamide catalyst for the oxidation of alcohols was developed. Reaction of alcohols with a catalytic amount of 2‐iodobenzamide in the presence of oxone as a co‐oxidant at room temperature gave the corresponding carbonyl compounds in excellent yields. Primary alcohols were directly converted into the corresponding carboxylic acids, whereas secondary alcohols were oxidized to ketones. A 2‐iodobenzoic acid‐type catalyst for alcohol oxidation at room temperature has not been reported before.