Copper(I)-catalyzed carboxylation of aryl- and alkenylboronic esters
Copper(I)-catalyzed carboxylation of aryl- and alkenylboronic esters
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DOI：
10.1021/ol800829q
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发表时间：
2008-07-03
期刊：
影响因子：
5.2
通讯作者：
Iwasawa, Nobuharu
中科院分区：
文献类型：
--
作者：
Takaya, Jun;Tadami, Satoshi;Iwasawa, Nobuharu
在CO（2）存在下，铜（I）催化芳基硼酸酯和烯基硼酸酯的羧化反应顺利进行，以高产率得到相应的羧酸。与相应的Rh（I）催化反应相比，该反应显示出更高的官能团耐受性的广泛通用性。
The copper(I)-catalyzed carboxylation reaction of aryl- and alkenylboronic esters proceeded smoothly under CO(2) to give the corresponding carboxylic acid in good yield. This reaction showed wide generality with higher functional group tolerance compared to the corresponding Rh(I)-catalyzed reaction.