Atomic and molecular clusters
Atomic and molecular clusters
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原子和分子簇
DOI：
10.4324/9780203484890
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发表时间：
1990
期刊：
影响因子：
--
通讯作者：
E. Bernstein
中科院分区：
文献类型：
--
作者：
E. Bernstein
1.超音速碳原子团束激光汽化团簇束和丰度分布。反应性研究。正团簇离子的光物理。FT-ICR实验。碳簇的UPS。C 60的光谱学。最后一个问题。2.主群聚类：一个综述。群集源和检测。集群分布。电离、碎裂和热力学。化学.团簇结构和能量的理论计算。团簇物种的结构和光谱。结束语。3.微波和红外光谱研究弱结合配合物的结构。4.货车德瓦耳斯团簇的红外预解离光谱。实验技术。高分辨率光谱学。小团簇振动理论。从头计算和正常模式。冻结场局部模式方法。团簇的量子模拟。水团簇理论。振动弛豫和预离解。振动预离解理论。大团簇的红外光谱。模拟大型集群。结论. 5.旋转彩虹，量子干涉，分子内振动弛豫和化学反应：所有在稀有气体卤素分子。卤素光谱学概述。实验方法的简要回顾。结构和键能。振动预解离动力学：实验结果。振动动力学的量子力学计算。振动预离解的经典和半经典模型。反应性半碰撞。更大的集群。凝聚相。后记6.团簇的光吸收和光电离。实验方法。谱光致电离。7.有机溶质/溶剂簇和溶质二聚体。实验方法。计算机模拟、建模和计算。溶质溶剂团簇的静态性质。光谱学和计算。溶质二聚体。溶质/溶剂团簇和二聚体的动力学性质-分子内振动再分布（IVR）和振动预解离（VP）。货车德瓦耳斯团簇中的化学反应。团簇的成核与生长。结论和展望。8.大分子团簇的光谱学和激发动力学。纯分子团簇的理论展望。实验方法。整齐的分子簇。掺杂的分子簇。团簇离子的光谱学。分子团簇光谱学进展展望。（各章还包括介绍和参考资料）。指数.
1. Supersonic Carbon Cluster Beams. Laser vaporization cluster beams and abundance distributions. Reactivity studies. Photophysics of the positive cluster ions. FT-ICR experiments. UPS of carbon clusters. Optical spectroscopy of C 60 . One parting question. 2. Main Group Clusters: A Review. Cluster sources and detection. Cluster distributions. Ionization, fragmentation, and thermodynamics. Chemistry. Theoretical calculations of cluster structures and energies. Structure and spectroscopy of cluster species. Concluding remarks. 3. The Structures of Weakly Bound Complexes as Elucidated by Microwave and Infrared Spectroscopy. 4. Infrared Predissociation Spectroscopy of van der Waals Clusters. Experimental techniques. High resolution spectroscopy. Theory of vibrations in small clusters. Ab-initio calculations and normal modes. Frozen field local mode methods. Quantum simulation of the clusters. Theory of water clusters. Vibrational relaxation and predissociation. Theory of vibrational predissociation. Infrared spectroscopy of large clusters. Simulation of large clusters. Conclusions. 5. Rotational Rainbows, Quantum Interference, Intramolecular Vibrational Relaxation and Chemical Reactions: All in Rare Gas-Halogen Molecules. Brief overview of halogen spectroscopy. Brief review of experimental methods. Structures and bond energies. Vibrational predissociation dynamics: experimental results. Quantum mechanical calculations of vibrational dynamics. Classical and semiclassical models for vibrational predissociation. Reactive half-collisions. Larger clusters. Condensed phases. Epilog. 6. Photoabsorption and Photoionization of Clusters. Experimental methods. Spectroscopy. Photoionization. 7. Organic Solute/Solvent Clusters and Solute Dimers. Experimental methods. Computer simulation, modeling and calculations. Static properties of solute solvent clusters. Spectroscopy and calculations. Solute dimers. Dynamical properties of solute/solvent clusters and dimers - intramolecular vibrational redistribution (IVR) and vibrational predissociation (VP). Chemical reactions in van der Waals clusters. Nucleation and growth of clusters. Conclusions and perspectives. 8. Spectroscopy and Excitation Dynamics of Large Molecular Clusters. Theoretical perspectives on neat molecular clusters. Experimental methodology. Neat molecular clusters. Doped molecular clusters. Spectroscopy of cluster ions. Outlook for advances in molecular cluster spectroscopy. (Chapters also include an introduction and references). Index.