Indium-Mediated Catalytic Enantioselective Allylation of N-Benzoylhydrazones Using a Protonated Chiral Amine (Retracted Article)

Indium-Mediated Catalytic Enantioselective Allylation of N-Benzoylhydrazones Using a Protonated Chiral Amine (Retracted Article)
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DOI:
10.1021/ja1035336
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发表时间:
2010-09-08
影响因子:
15
通讯作者:
Jang, Doo Ok
Jang, Doo Ok
中科院分区:
化学1区
文献类型:
--
作者:
Kim, Sung Jun;Jang, Doo Ok

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发展了催化对映体选择性铟催化的N-苯甲酰肼与质子化的手性胺的烯丙化反应,得到了具有极高对映体选择性和化学产率的高烯丙基胺。
A catalytic enantioselective indium-mediated allylation of N-benzoylhydrazones in conjunction with a protonated chiral amine affording enantioenriched homoallylic amines with an extremely high level of enantioselectivity and chemical yield was developed.