Graphite oxide as an efficient and durable metal-free catalyst for aerobic oxidative coupling of amines to imines
Graphite oxide as an efficient and durable metal-free catalyst for aerobic oxidative coupling of amines to imines
复制标题
氧化石墨作为一种高效耐用的无金属催化剂，用于胺与亚胺的有氧氧化偶联
DOI：
10.1039/c2gc16681j
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发表时间：
2012-01-01
期刊：
影响因子：
9.8
通讯作者：
Fan, Kang-Nian
中科院分区：
文献类型：
--
作者：
Huang, Hai;Huang, Jun;Fan, Kang-Nian
氧化石墨是一种高效、可重复使用、经济实惠的多相催化剂，用于胺的直接无金属转化，以分子氧为末端氧化剂，在温和、清洁的条件下提供相应的亚胺。该方法简单、经济、环保，为亚胺及其衍生物的方便合成提供了实用的优势。
Graphite oxide was found to be a highly efficient, reusable and cost-effective heterogeneous catalyst for the direct metal-free transformation of amines to afford the corresponding imines under mild and neat conditions with molecular oxygen as the terminal oxidant. This method is simple, economic and environmentally benign, resulting in practical advantages for the convenient synthesis of imines and their derivatives.