The First [5]Supercyclodextrin Whose Cyclopentameric Array Is Held Only by a Mechanical Bond
The First [5]Supercyclodextrin Whose Cyclopentameric Array Is Held Only by a Mechanical Bond
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第一个[5]超级环糊精，其环五聚体阵列仅通过机械键固定
DOI：
10.1246/cl.2001.1264
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发表时间：
2001
影响因子：
1.6
通讯作者：
Y. Sakata
中科院分区：
文献类型：
--
作者：
T. Kaneda;Takashi Yamada;Tatsuhiko Fujimoto;Y. Sakata
以一种新型的两性单体2为截流剂，以5 -偶氮偶联的方式合成了首个纳米级环五聚体阵列的[5]超环糊精1s，并通过色谱分离，利用质谱、二维核磁共振和可见光谱方法对其进行了表征。
The first [5]supercyclodextrin 1s whose nano-sized cyclopentameric array is held only by a mechanical bond was synthesized by the pentakis-azo coupling of a new hermaphrodite monomer 2 with 2-naphthol as a stopper, isolated by chromatography, and characterized by MS, 2D NMR, and vis spectral methods with the help of computer simulation.