State-of-the-Art Advances and Challenges of Iron-Based Metal Organic Frameworks from Attractive Features, Synthesis to Multifunctional Applications
State-of-the-Art Advances and Challenges of Iron-Based Metal Organic Frameworks from Attractive Features, Synthesis to Multifunctional Applications
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铁基金属有机框架材料从有吸引力的特性、合成到多功能应用的最新进展和挑战
DOI：
10.1002/smll.201803088
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发表时间：
2019
期刊：
影响因子：
13.3
通讯作者：
Zeng Guangming
中科院分区：
文献类型：
--
作者：
Xia Qi;Wang Hou;Huang Binbin;Yuan Xingzhong;Zhang Jingjing;Zhang Jin;Jiang Longbo;Xiong Ting;Zeng Guangming
金属有机骨架（MOFs）是一种新颖的有机-无机多孔材料，它是由金属中心和有机连接基团通过配位络合反应构筑而成。在众多的金属有机骨架材料中，含铁金属有机骨架材料（Fe-MOFs）具有结构多样、毒性低、稳定性好、功能性强等特点，在实际应用中具有很大的潜力。本文综述了近年来Fe-MOFs在功能、合成和多功能应用方面的研究进展。根据构建块的设计，讨论了具有多孔性和定制功能的Fe-MOFs。介绍了溶剂热法、水热法、微波法和干凝胶转化法四种合成方法。最后，阐述了Fe-MOFs在锂离子电池、传感器、气体储存、气液分离和催化方面的应用，重点介绍了其机理。其目的是为在更实际的应用中扩展Fe-MOFs提供前景。
Metal organic frameworks (MOFs), as an original kind of organic–inorganic porous material, are constructed with metal centers and organic linkers via a coordination complexation reaction. Among uncountable MOF materials, iron‐containing metal organic frameworks (Fe‐MOFs) have excellent potential in practical applications owing to their many fascinating properties, such as diverse structure types, low toxicity, preferable stability, and tailored functionality. Here, recent research progresses of Fe‐MOFs in attractive features, synthesis, and multifunctional applications are described. Fe‐MOFs with porosity and tailored functionality are discussed according to the design of building blocks. Four types of synthetic methods including solvothermal, hydrothermal, microwave, and dry gel conversion synthesis are illustrated. Finally, the applications of Fe‐MOFs in Li‐ion batteries, sensors, gas storage, separation in gas and liquid phases, and catalysis are elucidated, focusing on the mechanism. The aim is to provide prospects for extending Fe‐MOFs in more practical applications.