VALENCE DELOCALIZATION IN MIXED-VALENCE 1,6′-DIIODOBI FERROCENIUM TRIIODIDE
VALENCE DELOCALIZATION IN MIXED-VALENCE 1,6′-DIIODOBI FERROCENIUM TRIIODIDE
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混合价 1,6-二碘二茂铁三碘化物中的价态离域
DOI：
10.1002/chin.198548062
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发表时间：
1985
期刊：
影响因子：
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通讯作者：
C. Pierpont
中科院分区：
文献类型：
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作者：
T. Dong;M. J. Cohn;D. Hendrickson;C. Pierpont
在过去的两年中，我们对混合价过渡金属配合物中控制分子内电子转移的因素有了更清楚的了解。在最近的一篇论文3中，研究表明，对于氧中心的混合价络合物[Fe 30（02 CCH 3）6（4-Et-py）3]（4-Et-py），其中4-Et-py是4-乙基吡啶，固态结构从低温下的静态无序到高温下的动态无序的转变显著影响分子内电子转移速率。类似的观察现在已经在其他几个混合价三核
Discoveries made over the past 2 years have contributed to a much clearer understanding of factors that control intramolecular electron transfer in mixed-valence transition-metal complexes. In a very recent paper3 it was shown that for the oxo-centered mixed-valence complex [Fe30 (02CCH3) 6 (4-Et-py) 3](4-Et-py), where 4-Et-py is 4-ethylpyridine, a transformation in the solid-state structure from statically disordered at low temperatures to dy-namically disordered at high temperatures dramatically affects the intramolecular electron-transfer rate. Similar observations have now been made on several other mixed-valence trinuclear