Selective palladium-catalyzed arylation(s) of benzaldehyde derivatives by N-heterocarbene ligands

Selective palladium-catalyzed arylation(s) of benzaldehyde derivatives by N-heterocarbene ligands
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DOI:
10.1016/j.tetlet.2005.02.023
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发表时间:
2005-03-28
影响因子:
1.8
通讯作者:
Çetinkaya, B
Çetinkaya, B
中科院分区:
化学4区
文献类型:
--
作者:
Gürbüz, N;Özdemir, I;Çetinkaya, B

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在Pd(OAC)(2)、咪唑啉氯化物(1-5)和Cs_2CO_3原位催化体系存在下,芳香醛的2-位或2,6-位被芳基氯或溴直接选择性芳基化。(c)2005爱思唯尔有限公司保留所有权利。
The 2- or 2,6-position(s) of aromatic aldehydes were directly and selectively arylated with aryl chlorides or bromides in the presence of a catalytic system prepared in situ from Pd(OAC)(2), imidazolinium chlorides (1-5) and Cs2CO3. (c) 2005 Elsevier Ltd. All rights reserved.