Formation of novel P-functionalised ligands by insertion of CyNC into the ZrP bonds of [Cp°2ZrCl(PHCy)] (Cp°=η5-C5EtMe4, Cy=cyclohexyl) and [Cp′2ZrCl(PHTipp)] (Cp′=η5-C5H4Me, Tipp=2,4,6-Pri3C6H2). Molecular structures of [Cp°2ZrCl{η2-NCyC(PHCy)}] and [Cp′2Zr(Cl){η2-NCyC(PHTipp)}]
Formation of novel P-functionalised ligands by insertion of CyNC into the ZrP bonds of [Cp°2ZrCl(PHCy)] (Cp°=η5-C5EtMe4, Cy=cyclohexyl) and [Cp′2ZrCl(PHTipp)] (Cp′=η5-C5H4Me, Tipp=2,4,6-Pri3C6H2). Molecular structures of [Cp°2ZrCl{η2-NCyC(PHCy)}] and [Cp′2Zr(Cl){η2-NCyC(PHTipp)}]
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通过将 CyNC 插入 [Cp°2ZrCl(PHCy)] (Cp°=η5-C5EtMe4, Cy=环己基) 和 [Cp′2ZrCl(PHTipp)] (Cp′=η5) 的 ZrP 键中形成新型 P 功能化配体-C5H4Me, Tipp=2,4,6-Pri3C6H2) [Cp°2ZrCl{η2-NCyC(PHCy)}] 和 [Cp′2Zr(Cl){η2-NCyC(PHTipp)}] 的分子结构。
DOI:
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发表时间:
2000
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通讯作者:
E. Hey‐Hawkins
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作者:
Ulrike Segerer;S. Blaurock;J. Sieler;E. Hey‐Hawkins