Syntheses and Properties of Micro/Nanostructured Crystallites with High-Energy Surfaces
Syntheses and Properties of Micro/Nanostructured Crystallites with High-Energy Surfaces
复制标题
高能表面微纳结构微晶的合成及性能
DOI：
10.1002/adfm.201001243
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发表时间：
2010-11-09
影响因子：
19
通讯作者：
Zheng, Lan-Sun
中科院分区：
文献类型：
--
作者：
Jiang, Zhi-Yuan;Kuang, Qin;Zheng, Lan-Sun
近年来，具有高能晶面的微/纳米结构微晶的合成受到了特别的关注，因为高能晶体表面通常具有迷人的表面增强特性，并且在催化、光电器件和能量转换等方面具有很好的应用前景。本文综述了近年来表面/形貌控制合成领域的研究进展，重点介绍了纤锌矿、岩盐、金红石、金红石和面心立方五种无机功能材料的高能晶体表面。结合理论和实验研究结果以及晶体结构模型，进一步讨论了高能表面材料的表面依赖性化学/物理性质的内在原因。
Recently, special attention has been paid to the syntheses of micro/nanostructured crystallites with high-energy crystal facets, because high-energy crystal surfaces usually exhibit fascinating surface-enhanced properties and have promising applications in catalysis, photoelectrical devices, and energy conversion, etc. With particular emphasis on the results obtained by the authors' research group, this feature article gives a brief review of recent progress in the field of surface/morphology controlled syntheses, focusing on high-energy crystal surfaces of five kinds of inorganic functional material, with the wurtzite, rocksalt, anatase, rutile, and face-centered cubic structures, respectively. Combined with the theoretical and experimental research results as well as crystal structure models, the intrinsic causes for surface-dependent chemical/physical properties of those materials with high-energy surfaces are further discussed.