Passivity of Metals, Alloys, and Semiconductors

Passivity of Metals, Alloys, and Semiconductors
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金属、合金和半导体的钝化

DOI:
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发表时间:
2003
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影响因子:
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通讯作者:
A. W. Hassel
A. W. Hassel
中科院分区:
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文献类型:
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作者:
J. Schultze;A. W. Hassel

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The sections in this article are Introduction Definition of Passivity Survey of Systems General Principles of Passivity Thermodynamics and Bond Polarity Experimental Techniques for Characterization of Passive Films Thickness and Stoichiometry of Passive Films Chemistry, Crystal Structure and Aging Chemistry and Crystal Structure Aging Potential Distribution at the Interface Electrochemical and Chemical Reactions in Passive Systems Reactions Current Densities i Ionic Properties, Migration and Ion-Transfer Reactions Electronic Behavior and ETR Band Structure of Oxide Films Electron-Transfer Reactions ETR at Oxide Films Mixed Ionic/Electronic Conductivity Equivalent Circuit Diagrams Growth of Oxide Films and Ionic Migration Survey on the Growth of Oxide Films Insulating Passive Films on Metals: Growth, and Corrosion of Al as Example Thermodynamic Aspects A Survey on Oxide Formation from CVs The Film Formation Factor k Electrochemical Impedance Spectra EIS and Equivalent Circuit Diagram Kinetics of Film Growth Corrosion and Breakdown Porous Aluminum Oxide Other Types of Passive Aluminum Oxide Films, Anof, Modified Aluminum, Alloys Other Systems Other Metals Forming Insulating Oxide Films Semiconducting and Metallic Oxide Films on Metals Duplex Films Passivation with Participation of the Electrolyte Semiconductors Passivation of Alloys ITR at the Homogeneous Oxide/Electrolyte Interface: Corrosion and Modification Passive Corrosion in the Steady State Corrosion during Oxide Growth Oxide Reduction and Oxidation Modification of Oxide Films by ITR of Other Ions Corrosion at Inhomogeneous Films: Breakdown, Pitting and Localized Attack Microscopic and Molecular Reasons for Local Corrosion Dielectric Breakdown Collision ionization model Tunnel model for thin films Pitting Corrosion Cathodic Breakdown Laser Induced Breakdown or Oxide Growth Applications Conclusions Acknowledgments