Kinetic analysis of thermogravimetric data
Kinetic analysis of thermogravimetric data
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DOI：
10.1007/bf01912812
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发表时间：
1991-11
期刊：
影响因子：
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通讯作者：
J. Zsako;G. Liptay;C. Várhelyi;C. Novák;I. Gǎnescu
中科院分区：
文献类型：
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作者：
J. Zsako;G. Liptay;C. Várhelyi;C. Novák;I. Gǎnescu
合成了19种六氯铂酸与一价金属、芳香胺和杂环胺以及膦的盐，并通过化学分析进行了表征。用导数光谱法和差示扫描量热法研究了配合物的热分解。讨论了热解过程的本质。从热重曲线，动力学参数推导出不同阶段的热分解。
Nineteen salts of hexachloroplatinic acid with monovalent metals, aromatic and heterocyclic amines and phosphine were obtained and characterized by chemical analysis. The thermal decomposition of these complexes was studied by means of derivatograph and differential scanning calorimetry. The nature of the pyrolysis processes is discussed. From the TG curves, kinetic parameters were derived for different stages of the thermal decompositions.