Notable temperature effect on the stereoselectivity in the photochemical [2+2] cycloaddition reaction (Paterno-Buchi reaction) of 2,3-dihydrofuran-3-ol derivatives with benzophenone
Notable temperature effect on the stereoselectivity in the photochemical [2+2] cycloaddition reaction (Paterno-Buchi reaction) of 2,3-dihydrofuran-3-ol derivatives with benzophenone
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DOI：
10.1016/j.tetlet.2006.02.046
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发表时间：
2006-04-10
影响因子：
1.8
通讯作者：
Hayashi, T
中科院分区：
文献类型：
--
作者：
Abe, M;Terazawa, M;Hayashi, T
在2，3-二氢呋喃-3-醇衍生物1与二苯甲酮的光化学[2+2]环加成反应(Paterno-Buchi反应)中，报道了反式氧杂环己烷2与顺式氧杂环己烷2对立体选择性的显著温度效应(非线性Eyring图)。(C)2006爱思唯尔有限公司。保留所有权利。
A notable temperature effect (nonlinear Eyring plot) on stereoselectivity, trans-configured oxetane 2 versus cis-configured oxetane 2, is reported in the photochemical [2+2] cycloaddition reaction (Paterno-Buchi reaction) of 2,3-dihydrofuran-3-ol derivatives 1 with benzophenone. (c) 2006 Elsevier Ltd. All rights reserved.