Addition reaction of poly(2‐vinyl‐2‐oxazoline)s with thiols and carboxylic acids
Addition reaction of poly(2‐vinyl‐2‐oxazoline)s with thiols and carboxylic acids
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聚(2-乙烯基-2-恶唑啉)与硫醇和羧酸的加成反应
DOI：
10.1002/marc.1981.030020118
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发表时间：
1981
期刊：
影响因子：
--
通讯作者：
Atsushi Tōkairin
中科院分区：
文献类型：
--
作者：
T. Nishikubo;T. Iizawa;Atsushi Tōkairin
It is known that 2-oxazoline derivatives, containing an iminoether group in the ring, react with carboxylic acids'), thiols2), hydrogen halides3), epoxides4), and isocyanates'). Polymers have been prepared by cationic polymerization of 2-oxazolines6-"), by radical polymerization of 2-isopropenyl-2-oxazoline''9 12), and by polyaddition reactions of bis-2-oxazolines with dicarboxylic acids13) and with dithiols"). Although 2-oxazolinyl groups are useful functional groups, no reactions of pendant 2-oxazolinyl groups in a polymer chain have so far been reported except for the reaction with a carboxylic acid").
