A new class of fluorescent chemosensors based on the β-aminobisphosphonate receptor
A new class of fluorescent chemosensors based on the β-aminobisphosphonate receptor
复制标题
基于β-氨基二膦酸受体的新型荧光化学传感器
DOI：
10.1080/10610270802709352
复制
发表时间：
2009
影响因子：
3.3
通讯作者：
D. Durham
中科院分区：
文献类型：
--
作者：
John F. Callan;S. Kamila;Narinder Singh;R. Mulrooney;M. Mackay;Maedhbh C. Cronin;J. Dunn;D. Durham
研究了一系列具有β-氨基二膦酸盐受体的荧光传感器的光物理性质。这些化合物是根据光致电子转移传感器的荧光团-间隔器-受体格式设计的。传感器显示出不寻常的荧光强度- ph谱，这是由于受体-荧光团h键相互作用导致荧光猝灭。受体的数量和荧光团的性质都对传感器的pH值有影响。此外，化合物1也被证明对Cu2+离子有选择性，在pH 7.4的水中，灵敏度在微摩尔范围内。
The photophysical properties of a range of fluorescent sensors with β-aminobisphosphonate receptors have been studied. The compounds were designed according to the fluorophore–spacer–receptor format of photoinduced electron transfer-based sensors. The sensors displayed unusual fluorescence intensity–pH profiles that were attributed to a receptor–fluorophore H-bonding interaction that resulted in a quenching of fluorescence. The number of receptors and the nature of the fluorophore were both shown to have an effect on the pH profiles of the sensors. In addition, compound 1 was also shown to be selective for Cu2+ ions, in water at pH 7.4 with sensitivity in the micromolar range.
影响因子：
2.8
作者：
G. Habermehl
通讯作者：
G. Habermehl