New method for synthesis of aldehydes from esters by sodium diisobutyl-t-butoxyaluminum hydride

New method for synthesis of aldehydes from esters by sodium diisobutyl-t-butoxyaluminum hydride
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DOI:
10.1246/cl.2007.886
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发表时间:
2007-07-05
期刊:
影响因子:
1.6
通讯作者:
An, Duk Keun
An, Duk Keun
中科院分区:
化学4区
文献类型:
--
作者:
Song, Jung In;An, Duk Keun

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A new reducing agent, sodium diisobutyl-t-butoxyaluminum hydride (SDBBA), easily prepared by addition of sodium t-butoxide to DIBALH in THF at 0 degrees C or room temperature, readily reacts with representative esters to give the corresponding aldehydes in very good yields under mild conditions (0 degrees C).