Analytical Applications of Ionic Liquids
Analytical Applications of Ionic Liquids
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DOI：
10.1002/9780470027318.a9153
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发表时间：
2012-06
期刊：
影响因子：
--
通讯作者：
W. Acree;L. M. Grubbs
中科院分区：
文献类型：
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作者：
W. Acree;L. M. Grubbs
近年来，涉及离子液体（IL）的分析方法显着增加，部分原因是这类有机化合物独特的增溶作用和物理性质。本文综述了离子液体在分析化学中的不同应用。该演示文稿分为一个部分，描述了分析化学家感兴趣的液体的性质，然后是九个部分，分别涉及简单的两相液-液萃取，液相微萃取方法，基于离子液体的固相微萃取（SPME），薄层色谱（TLC）和高效液相色谱（HPLC）方法，电迁移方法，气-液色谱（GLC）方法，支撑的离子液体膜分离、质谱法、电化学法和光谱法。给出了每种应用的代表性样品，沿着具体参考所用的离子液体和分析的样品类型。
Analytical methods involving ionic liquids (ILs) have significantly increased in recent years, in part because of the unique solubilization and physical properties on this class of organic compounds. This article provides an overview of the different applications of ionic liquids in analytical chemistry. The presentation is divided into a section describing the properties of liquids that are of interest to analytical chemists, followed by nine sections pertaining to simple biphasic liquid-liquid extractions, liquid-phase microextraction methods, ionic liquid-based solid-phase microextractions (SPME), thin layer chromatographic (TLC) and high-performance liquid chromatographic (HPLC) methods, electromigration methods, gas-liquid chromatographic (GLC) methods, supported ionic liquid membrane separations, mass spectrometric methods, electrochemical methods, and spectroscopic methods. Representative samples of each application are given, along with specific references to the ionic liquid used and type of sample analyzed.