THE REACTION OF THE CHLOROMAGNESIUM DERIVATIVE OF CHLOROMAGNESIUM PHENYLACETATE WITH ISOCYANATES, CARBAMYL CHLORIDES AND ISOTHIOCYANATES
THE REACTION OF THE CHLOROMAGNESIUM DERIVATIVE OF CHLOROMAGNESIUM PHENYLACETATE WITH ISOCYANATES, CARBAMYL CHLORIDES AND ISOTHIOCYANATES
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DOI：
10.1021/ja01623a049
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发表时间：
1955-01-01
影响因子：
15
通讯作者：
ZINNES, H
中科院分区：
文献类型：
--
作者：
BLICKE, FF;ZINNES, H
由于已知普通类型的格氏试剂与异氰酸酯反应，因此可以预期，由苯乙酸和异丙基氯化镁制备的伊万诺夫试剂C6H6CH (MgCl)-COOMgCl (I)将以如下所示的方式与异氰酸酯反应。通过
Since it is known that the common type Grignard reagents react with isocyanates, 3 it was to be ex-pected that the Ivanov reagent, C6H6CH (MgCl)-COOMgCl (I), prepared from phenylacetic acid and isopropylmagnesium chloride, would react with isocyanates in the manner indicated below. By