Study of electrogenerated reactants using optically transparent electrodes
Study of electrogenerated reactants using optically transparent electrodes
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使用光学透明电极研究电生反应物
DOI：
10.1021/ar50103a001
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发表时间：
1976
影响因子：
18.3
通讯作者：
W. Heineman
中科院分区：
文献类型：
--
作者：
T. Kuwana;W. Heineman
1964 年，实验证明了使用光学透明电极 (OTE) 通过穿过电极的光对发电产物进行原位光谱观察。1 OTE 的想法从 R. N. Adams 教授的早期评论演变而来，大意是“拥有一个‘透明’电极来光谱识别正在形成的有色物质不是很好吗”。2 OTE 现在已经发展到相对成熟的程度。易于光学检查电生成物质以进行识别或表征。此外，在一些电化学扰动期间对光学吸光度形状随时间的变化的分析可以极大地帮助评估这些物质的机制和动力学。第一个 OTE 由玻璃表面组成，玻璃表面涂有一层透明的掺锑氧化锡薄膜（Nesa 玻璃）。它被用于透射和内反射光谱电化学实验^.^?^ 其他OTE，如红外锗板、玻璃上“画”的425铂薄膜、迷你网格（细线屏幕）？以及透明基板上的气相沉积金属膜8-12都有报道。在过去的10年中，OTE光谱电化学的进展包括：（1）各种OTE和光谱电化学电池的开发和表征；开发高灵敏度光学监测系统，包括计算机信号平均和快速扫描分光光度计 (2) 光学吸光度 (A) 与时间 (t) 的计算机分析；
In 1964 the use of an optically transparent electrode (OTE) for the in situ spectral observation of an electrogenerated product by light passing through the electrode was experimentally dem0nstrated.l This idea of an OTE evolved from an earlier remark by Professor R. N. Adams to the effect, “wouldn’t it be nice to have a ‘see-through’ electrode to spectrally identify the colored species being formed”.2 OTE’s have been developed now to the point where it is relatively easy to optically examine an electrogenerated species for identification or characterization purposes. Also, the analysis of the shape of the optical absorbance as a function of time during some electrochemical perturbation can greatly assist in evaluating the mechanism and kinetics of these species. The first OTE consisted of a glass surface which had been coated with a thin transparent film of antimonydoped tin oxide (Nesa glass). It was used for both transmission and internal reflection spectroelectrochemical experiment^.^?^ Other OTE’s such as germanium plates for infrared,425 thin platinum films “painted” on glass,” minigrids (thin wire screens)? and vapor-deposited metal films on transparent substrates8-12 have been reported. During the past 10 years, progress in OTE spectroelectrochemistry has included: (1) development and characterization of a variety of OTE and spectroelectrochemical cells; development of high sensitivity, optical monitoring systems including computer signal averaging and rapid scanning spectrophotometers; (2) computer analysis of optical absorbance ( A ) vs. time ( t )