A new ketone synthesis by palladium-catalyzed cross-coupling reactions of esters with organoboron compounds.
A new ketone synthesis by palladium-catalyzed cross-coupling reactions of esters with organoboron compounds.
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DOI：
10.1021/ol048513o
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发表时间：
2004-09
期刊：
影响因子：
5.2
通讯作者：
Hiroto Tatamidani;F. Kakiuchi;N. Chatani
中科院分区：
文献类型：
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作者：
Hiroto Tatamidani;F. Kakiuchi;N. Chatani
[反应：见正文] 描述了钯催化的2-吡啶酯与有机硼化合物的偶联反应。该反应与各种官能团相容，反应条件温和。氮原子与Pd的配位是有效反应的关键步骤。
[reaction: see text] The palladium-catalyzed coupling reaction of 2-pyridyl esters with organoboron compounds is described. The reaction is compatible with various functional groups and proceeds under mild reaction conditions. The coordination of the nitrogen atom to Pd is a key step for efficient reaction.