Catalysts with mixed ligands on immobilized supports. Electronic and steric advantages

Catalysts with mixed ligands on immobilized supports. Electronic and steric advantages
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DOI:
10.1021/ol027475a
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发表时间:
2003-02-20
期刊:
影响因子:
5.2
通讯作者:
Blossey, EC
Blossey, EC
中科院分区:
化学1区
文献类型:
--
作者:
Doyle, MP;Yan, M;Blossey, EC

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[图]具有混合手性配体的固定化Dr(II)催化剂提高了环丙烷化和碳氢插入反应的反应活性(AH=氮杂二酮),并影响了立体选择性。
[GRAPHICS]Immobilized dirhodium(II) catalysts having mixed chiral ligands enhance reactivity (AH = azetidinone) and influence stereoselectivity in cyclopropanation and carbon-hydrogen insertion reactions.