Kinetic self-assembly: selective cross-catenation of two sterically differentiated Pd(II)-coordination rings.

Kinetic self-assembly: selective cross-catenation of two sterically differentiated Pd(II)-coordination rings.
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DOI:
10.1002/anie.200460671
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发表时间:
2004-09
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影响因子:
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通讯作者:
A. Hori;K. Yamashita;M. Fujita
A. Hori;K. Yamashita;M. Fujita
中科院分区:
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文献类型:
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作者:
A. Hori;K. Yamashita;M. Fujita

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魔环:两个不同的 Pd III 连接配位环(见图)的动力学控制交叉连接的技巧在于,由于配体的空间位阻,两个环的连接速率存在巨大差异。
Magic rings: The trick of kinetically controlled cross-catenation of two different Pd III-linked coordination rings (see picture) lies in the large difference in the catenation rate of the two rings as a result of steric hindrance of the ligands.