Sodium phosphides as efficient and sustainable catalysts for hydrophosphination of alkynes

Sodium phosphides as efficient and sustainable catalysts for hydrophosphination of alkynes
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DOI:
10.1016/j.checat.2022.06.022
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发表时间:
2022-07
期刊:
Chem Catalysis
影响因子:
--
通讯作者:
S. Asako
S. Asako
中科院分区:
其他
文献类型:
--
作者:
S. Asako

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作为地球上最丰富的碱金属,钠作为稀有锂的可持续替代品越来越受到关注。最近,inCell Reports Physical Science,Mulvey及其同事合成了一系列具有刘易斯碱供体的二苯基膦酸钠,并证明了它们作为炔的氢膦化的有效催化剂的用途。
As the most abundant alkali metal on Earth, sodium is gaining increasing attention as a sustainable alternative to rarer lithium. Recently, inCell Reports Physical Science, Mulvey and co-workers synthesized a series of sodium diphenylphosphides with Lewis base donors and demonstrated their use as efficient catalysts for hydrophosphination of alkynes.