Arsine toxicity: chemical and mechanistic implications.

Arsine toxicity: chemical and mechanistic implications.
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砷化氢毒性:化学和机械影响。

DOI:
10.1080/15287399509532045
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发表时间:
1995
期刊:
Journal of toxicology and environmental health.
影响因子:
--
通讯作者:
Carter,DE
Carter,DE
中科院分区:
--
文献类型:
--
作者:
Klimecki,WT;Carter,DE

文献摘要

参考文献

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背景砷气体在工业毒理学中占有重要地位。自1775年发现以来,它一直被认为是最有效、最难检测到的气体毒物之一,这一点令人怀疑。在化学家舍勒发现砷之后,1815年,一位名叫切伦的德国化学家意外地将自己暴露在这种气体中,从而声称自己是第一个报告的受害者。九天后,他去世了。1873年和1902年记录了工业中毒(Buchanon,1962)。在这两起事件中,工人都是在向含银矿石中添加了酸后暴露的。到1959年,文献中已报道了310例砷中毒(Elkins&Fahy,1967)。目前,劳工统计局没有在其工业死亡原因数据库中具体列出接触砷的情况,因此目前砷引起的工伤或死亡的程度尚不清楚。
BACKGROUNDArsine gas holds an important place in industrial toxicology. Since its discovery in 1775 it has held the dubious distinction of being one of the most potent and least inherently detectable gaseous toxicants. Following its discovery by the chemist Scheele, arsine claimed its first reported victim when, in 1815, a German chemist named Cehlen accidentally exposed himself to the gas. Nine days later he died. Industrial intoxications were recorded in 1873 and 1902 (Buchanon, 1962). In both instances workers became exposed after adding acids to silver-containing ores. By 1959, 310 cases of arsine intoxication had been reported in the literature (Elkins & Fahy, 1967). Currently the Bureau of Labor Statistics does not specifically list arsine exposure in their database of causes of industrial fatalities, so the current extent of arsine-induced industrial injuries or fatalities is unknown.
DOI: 10.1007/bf00248379
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影响因子: --
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